Selective TiO₂ Nanolayer Coating by Polydopamine Modification for Highly Stable Ni‐Rich Layered Oxides

Abstract

Ni-rich layered oxides are promising cathode materials for developing high-energy lithium-ion batteries. To overcome the major challenge of surface degradation, a TiO₂ surface coating based on polydopamine (PDA) modification was investigated in this study. The PDA precoating layer had abundant OH catechol groups, which attracted Ti(OEt)₄ molecules in ethanol solvent and contributed towards obtaining a uniform TiO₂ nanolayer after calcination. Owing to the uniform coating of the TiO₂ nanolayer, TiO₂ -coated PDA-LiNi_0.6 Co_0.2 Mn_0.2 O₂ (TiO₂ -PNCM) displayed an excellent electrochemical stability during cycling under high voltage (3.0-4.5 V vs. Li⁺ /Li), during which the cathode material undergoes a highly oxidative charge process. In addition, TiO₂ -PNCM exhibited excellent cyclability at elevated temperature (60 °C) compared with the bare NCM. The surface degradation of the Ni-rich cathode material, which is accelerated under harsh cycling conditions, was effectively suppressed after the formation of an ultra-thin TiO₂ coating layer.