Publication | Open Access
Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions
364
Citations
48
References
2019
Year
Materials ScienceInorganic ChemistryOrr ProcessOxygen Reduction ReactionEngineeringAtomic Interface EffectOxidation ResistanceHeterogeneous CatalysisCu Oxidation StateCatalytic SitesSingle-atom CatalystCatalysisChemistryCatalytic ProcessElemental MetalElectrochemistry
By the <italic>in situ</italic> X-ray absorption results, the gradually decrease of Cu oxidation state under applied potential implied that low-valence Cu (+1) species in the atomic interface of Cu–N<sub>4</sub>–C<sub>8</sub>S<sub>2</sub> may work as the catalytic sites during an ORR process.
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