Tunable Aggregation‐Induced Emission of Imidazole Hydrazones by pH and Anions

Abstract

Aggregation-induced emission (AIE) materials have drawn great attention for applications as organic light-emitting diodes (OLED) and probes. The applications are, however, restricted by the complex syntheses and hydrophobic properties. Herein, a one-step synthesis of an AIE material based on imidazole hydrazone is assessed. Protonation of the imidazole-H leads to emission color change from yellow to green in the solid state. The emission color is recovered upon imidazole-H⁺ deprotonation. Moreover, the emission wavelength shifts from 532 to 572 nm by anion exchange. In addition, an enhanced emission (Φ_F up to 22.6 %) was obtained with the Br^- anion compared with NTf₂ ^- , SbCl₅ ^- , PF₆ ^- , and OTf^- anions. X-ray crystallography studies together with theoretical calculations show that the enhanced emission of hydrazone salts arises from strong hydrogen bonding between the hydrazone proton and the halide ion (Cl^- or Br^- ).