SnS Nanosheets Confined Growth by S and N Codoped Graphene with Enhanced Pseudocapacitance for Sodium-Ion Capacitors

Abstract

Layered tin monosulfide (SnS) is a promising anode material for sodium-ion batteries because of its high theoretical capacity of 1020 mA h g^-1. Its large interlayer spacing permits fast sodium-ion transport, making it a viable candidate for sodium-ion capacitors (SICs). In this work, we designed and synthesized oriented SnS nanosheets confined in graphene in the presence of poly(diallyl dimethyl ammonium chloride) by electrostatic self-assembly during hydrothermal growth. SnS nanosheets growing along (<i>l</i>00) and (0<i>l</i>0) directions are suppressed because of the confinement by graphene, which exhibit smaller thickness and particle size. These nanostructures expose abundant open edges because of the presence of Sn⁴⁺-O, which offers rich active sites and Na⁺ easy transport pathways. Vacancies formed at these edges along with S and N codopants in the graphitic structure synergistically promoted Na⁺ surface adsorption/desorption. Such nanocomposites with SnS nanosheets confined by N,S codoped graphene demonstrated significantly enhanced pseudocapacitance. The SICs delivered excellent energy densities of 113 and 54 W h kg^-1 at power densities of 101 and 11 100 W kg^-1, respectively, with 76% capacity retention after 2000 cycles at 1 A g^-1.