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Ultrathin LiV<sub>2</sub>O<sub>4</sub> Layers Modified LiNi<sub>0.5</sub>Co<sub>0.2</sub>Mn<sub>0.3</sub>O<sub>2</sub> Single‐Crystal Cathodes with Enhanced Activity and Stability
53
Citations
50
References
2019
Year
EngineeringSolid-state ChemistryChemistryChemical EngineeringUltrathin Liv 2Enhanced ActivityDeep ChargeMaterials ScienceMaterials EngineeringBattery Electrode MaterialsSurface ElectrochemistryAdvanced Electrode MaterialLithium-ion BatteryLithium-ion BatteriesEnergy StorageO 4Solid-state BatteryElectrochemical ProcessEnergy MaterialElectrochemistryLi-ion Battery MaterialsCathode MaterialsElectrochemical Energy StorageBatteriesAnode MaterialsFunctional Materials
Abstract Nickel–cobalt–manganese ternary cathode materials for lithium‐ion batteries are prone to detrimental side reactions and deterioration performance at deep charge. Coating is one of the effective methods to boost electrochemical performance of materials. This work conducts an ultrathin LiV 2 O 4 layer on the single‐crystal LiNi 0.5 Co 0.2 Mn 0.3 O 2 (NCM523) particles and scrutinizes the optimal coating amount. It turns out that 0.3 wt% LiV 2 O 4 ‐modified NCM523 cathode achieves a reversible discharging capacity of 131.2 mAh g −1 after 100 cycles (3.0–4.5 V vs Li/Li + ), with a capacity retention of 80% (which is 50% higher than that of the pristine sample). The experimental data suggest that this lithium vanadate coating technique provides an innovative strategy to boost the performance of NCM cathodes.
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