Publication | Open Access
A Divergent Duo: Palladium Catalyzed Carboamination in Enantioselective Desymmetrization and Regiodivergent Catalysis
12
Citations
36
References
2019
Year
Divergent DuoEngineeringOrganic ChemistryChemistryRegiodivergent CatalysisChemical EngineeringRegiodivergent SynthesisOrganometallic CatalysisPalladium Catalyzed CarboaminationHybrid MaterialsDiversity-oriented SynthesisCatalysisAsymmetric CatalysisEnantioselective SynthesisCatalytic SynthesisRegioselective CatalystNatural Sciences/Josiphos SystemSynthetic Chemistry
Abstract We describe a regiodivergent synthesis of pseudo ‐C 2 ‐symmetrical and pseudo ‐meso bis‐indoline scaffolds from norbornadiene and substituted o ‐iodo‐anilines. The Pd(0)/Josiphos system enables the highly regioselective catalyst controlled carboaminations required for the two step synthesis of the scaffolds.
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