Highly Active Core–Shell Carbon/NiCo₂O₄ Double Microtubes for Efficient Oxygen Evolution Reaction: Ultralow Overpotential and Superior Cycling Stability

Abstract

Developing highly efficient electrocatalysts with earth abundant elements for oxygen evolution reaction (OER) is a promising way to store light or electrical energy in the form of chemical energy. Here, a new type of electrocatalyst with core-shell carbon/NiCo₂ O₄ double microtubes architecture is successfully synthesized through a hydrothermal method combined with the calcination process with wet tissues as the template and carbon resource. The outer NiCo₂ O₄ nanosheet arrays contain abundant defects, which come from reduction of the carbon in wet tissues. This indicates that carbon is a very excellent defect inducer. The inner carbon microtubes can act as the robust structure skeleton and these core-shell double microtubes provide abundant diffusion channels for oxygen and electrolyte, both of which contribute to improving the stability by avoiding damage to the electrode from produced O₂ bubbles and the collapse of the outer NiCo₂ O₄ microtubes. Electrochemical results show that the electrode, core-shell carbon/NiCo₂ O₄ double microtubes loaded on carbon cloth, exhibits prominent electrocatalytic activity with an overpotential of only 168 mV at 10 mA cm^-2 and a Tafel slope as low as 57.6 mV dec^-1 in 1.0 mol L^-1 KOH. This new type of electrocatalyst possesses great potential in water electrolyzers and rechargeable metal-air batteries.