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Lithium-desorption mechanism in LiMn<sub>2</sub>O<sub>4</sub>, Li<sub>1.33</sub>Mn<sub>1.67</sub>O<sub>4</sub>, and Li<sub>1.6</sub>Mn<sub>1.6</sub>O<sub>4</sub> according to precisely controlled acid treatment and density functional theory calculations
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Citations
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References
2019
Year
Materials ScienceChemical EngineeringEngineeringLi-ion Battery MaterialsLithium-ion BatteryLithium-ion BatteriesVacant 8AEnergy StoragePhysical ChemistryLithium-desorption MechanismElectrochemical Energy StorageControlled Acid TreatmentBatteriesChemistrySolid-state BatteryEnergy MaterialElectrochemistry
Li<sub>8a</sub><sup>+</sup> preferred to be replaced by H<sup>+</sup> than Li<sub>16d</sub><sup>+</sup>, desorbed Li<sup>+</sup> preferred to diffuse out through vacant 8a sites.
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