Electrostatic Assembly of a Titanium Dioxide@Hydrophilic Poly(phenylene sulfide) Porous Membrane with Enhanced Wetting Selectivity for Separation of Strongly Corrosive Oil–Water Emulsions

Abstract

The efficient treatment of oil-water emulsions in extreme environments, such as strongly acidic and alkaline media, remains a widespread concern. Poly(phenylene sulfide) (PPS)-based porous membranes with excellent resistance to chemicals and solvents are promising for settling this challenge. However, the limited hydrophilicity and the poor hydrated ability of the hydrophilic PPS (h-PPS) membranes reported in the literature prevents them from separating oil-water emulsions with high efficiency, large fluxes, and good antifouling performances. In this study, a firm rough TiO₂ layer is constructed on a h-PPS membrane via electrostatic assembly to improve the surface hydrophilization. The introduction of the TiO₂ layer increases the wetting selectivity and decreases the oil adhesion, which makes it capable to efficiently treat oil-in-water emulsions (efficiency > 98%). Most importantly, the underwater critical oil intrusion pressure almost doubled after the incorporation of the TiO₂ layer, which allows the membrane to withstand pressurized filtration, achieving a high flux of ∼4000 L m^-2 h^-1. This is more than 2 orders of magnitude larger than the flux of the reported h-PPS. Furthermore, the TiO₂@h-PPS membrane displays long-term stability in separating oil-water emulsions in strong acid and strong alkali, showing a promising prospect for the treatment of strongly corrosive emulsions.