Polymer Composites · 2019 · 19 citations · 13 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials CharacterizationPolymer ChemistryPolymer MaterialsDielectric MaterialsDielectric PropertiesDielectric ResponseDielectricsElectrical CharacterizationInsulation MaterialsDielectric ConstantDielectric Loss MeasurementDielectric StrengthElectrical Insulation MaterialsEpoxy Resin InsulationEpoxy ResinsInsulation PerformancePartial Discharge
Abstract To investigate the variation of dielectric properties of epoxy resin impregnated paper insulation in different stages of partial discharge (PD) development, a PD experimental platform was established and epoxy resin impregnated paper insulation samples were prepared. According to the discharge amount, the number of discharges and discharge phenomena during the PD process, the PD process is divided into an initial stage, development stage, burst stage, and near‐breakdown stage. The variations of dielectric constant and dielectric loss factor of the sample during different PD development stages were measured by frequency domain dielectric spectrum tester. Scanning electron microscopy was used to observe the microscopic morphological changes of the samples at different stages of PD development. The surface characteristic functional groups at different stages of PD development of the sample were determined by Fourier transform infrared spectroscopy. The results show that: as the PD progresses, the insulation performance deteriorates; under continuous bombardment by high‐speed electrons, the network structure of the fiber surface and the epoxy molecular chain are destroyed, causing the weakening of the binding force between the molecular chains, and the short‐chain structure formed by cracking has a stronger steering ability. Under the continuous action of PD, the inside of the long‐chain molecule breaks and oxidizes, and a large number of small molecules, such as free radicals and monoglucose, are formed. The decrease in the molecular weight of the polymer leads to the weakening of the interaction between the molecules, resulting in an increase in polarization, a large dielectric constant, and an increase in the dielectric loss factor.
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