Helical assembly of a dithienogermole exhibiting switchable circularly polarized luminescence

Kyohei Hirano, Toshiaki Ikeda, Naoka Fujii, T. Hirao, Masashi Nakamura, Yohei Adachi, Joji Ohshita, Takeharu Haino

Chemical Communications · 2019 · 21 citations · 31 references

Concepts

Abstract

Dithienogermole derivatives S- and R-1 possessing phenylisoxazoles and chiral side chains were synthesized. The helical assembly of 1 in methylcyclohexane exhibited circularly polarized luminescence (CPL). The CPL signals of the assembly in the elongation regime were inverted with respect to those in the nucleation regime.

References

31