Tying the alkoxides together: an iron complex of a new chelating bulky bis(alkoxide) demonstrates selectivity for coupling of non-bulky aryl nitrenes

Abstract

New chelating bis(alkoxide) ligand H₂[OO]^Ph and its iron(ii) complex Fe[OO]^Ph(THF)₂ are described. The coordination of the ligand to the metal center is reminiscent of the coordination of two monodentate alkoxides in previously reported Fe(OR)₂(THF)₂ species. Fe[OO]^Ph(THF)₂ catalyzes selective and efficient dimerization of non-bulky aryl nitrenes to yield the corresponding azoarenes.