A Cross-Linked Triphenylamine-Based Polymer Cathode Material with Dual Anion-Cation Reversible Insertion for Lithium Ion Battery

Abstract

A cross-linked triphenylamine polymer poly[N,N'-bis(4-diphenylaminophenyl) naphthalene-1,4,5,8-tetracarboxylic diimide] cathode material with dual anion-cation reversible insertion is polymerized from monomer N,N'-bis(4-diphenylaminophenyl) naphthalene-1,4,5,8-tetracarboxylic diimide by chemical oxidative polymerization, which has a very low solubility in common organic solvents and electrolytes. The triphenylamine unit in the polymer can reversibly dope/dedope the PF6− anion, while the naphthalimide unit can reversibly insert/extract the lithium cation. The lithium ion half-cells with the polymer as a cathode and the lithium foil as an anode are assembled and the electrochemical properties are tested. For comparison, the electrochemical properties of monomer are studied. Thanks to its cross-linked network structure, the electrochemical performance of polymer is much better than that of its monomer. The polymer has excellent cycle performance, the initial discharge specific capacity is 140 mAh g−1, which is close to its theoretical specific capacity, and the capacity can still be maintained at 125 mAh g−1 after 100 cycles, suggesting that this polymer is a potential cathode material for lithium ion batteries.