Physical Review E · 2009 · 58 citations · 36 references
Natural SciencesMathematicsDynamical SystemsInformation TheoryThermodynamicsEntropyIrreversible ProcessesIrreversible ThermodynamicsNon-equilibrium ThermodynamicsStatistical MechanicsStatistical ThermodynamicsEntropy ProductionEquilibriumExactly Solvable ModelsFinite TimeFluctuation TheoremsFluctuation TheoryIrreversibility In Statistical MechanicsThermodynamic Entropy
The total entropy production fluctuations are studied in some exactly solvable models. For these systems, the detailed fluctuation theorem holds even in the transient state, provided initially that the system is prepared in thermal equilibrium. The nature of entropy production during the relaxation of a system to equilibrium is analyzed. The averaged entropy production over a finite time interval gives a better bound for the average work performed on the system than that obtained from the well-known Jarzynski equality. Moreover, the average entropy production as a quantifier for information theoretic nature of irreversibility for finite time nonequilibrium processes is discussed.
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Nonequilibrium Equality for Free Energy Differences
Christopher Jarzynski · Physical Review Letters · 1997 · 5.4K citations · Full text
Gavin E. Crooks · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics · 1999 · 2.6K citations · Full text