Environment-friendly, co-catalyst- and solvent-free fixation of CO₂ using an ionic zinc(<scp>ii</scp>)–porphyrin complex immobilized in porous metal–organic frameworks

Abstract

Development of a heterogeneous catalyst composed of a [Zn(<sc>ii</sc>)NMeTPyP]⁴⁺[I⁻]₄ complex immobilized in PCN-224 for environment-friendly, co-catalyst-free fixation of CO₂ is reported.