Proceedings of the National Academy of Sciences · 2019 · 121 citations · 39 references
Natural SciencesPhysicsCondensed Matter PhysicsSolid State PhysicsThermodynamicsPhase TransitionsStates Of MatterCoherence LengthCritical TemperatureGlassy DynamicsGlassy StateInternal EnergyNonequilibrium DynamicsSpin Glass BehaviorSpin Glasses
The Mpemba effect occurs when a hot system cools faster than an initially colder one, when both are refrigerated in the same thermal reservoir. Using the custom-built supercomputer Janus II, we study the Mpemba effect in spin glasses and show that it is a nonequilibrium process, governed by the coherence length ξ of the system. The effect occurs when the bath temperature lies in the glassy phase, but it is not necessary for the thermal protocol to cross the critical temperature. In fact, the Mpemba effect follows from a strong relationship between the internal energy and ξ that turns out to be a sure-tell sign of being in the glassy phase. Thus, the Mpemba effect presents itself as an intriguing avenue for the experimental study of the coherence length in supercooled liquids and other glass formers.
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