Organic Chemistry Frontiers · 2019 · 48 citations · 72 references
Natural SciencesChemistryCatalysisOrganic ChemistryCoordination ChemistryCross-coupling ReactionsHeterocycle SynthesisHeterocyclic ChemistryHeterocyclic CompoundsOrganic SynthesisCopper-catalyzed CouplingCopper-catalyzed OxidationHeterocycle FunctionalizationMild Reaction Conditions
Copper-catalyzed 1,3-aminoazidation of arylcyclopropanes with <italic>N</italic>-fluorobenzenesulfonimide (NFSI) and trimethylsilyl azide (TMSN<sub>3</sub>) has been developed, providing various 1,3-diamine derivatives in moderate to good yields under mild conditions.
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