Influence of Blend Composition and Silica Nanoparticles on the Morphology and Gas Separation Performance of PU/PVA Blend Membranes

Abstract

Polymer blending and mixed-matrix membranes are well-known modification techniques for tuning the gas separation properties of polymer membranes. Here, we studied the gas separation performance of mixed-matrix membranes (MMMs) based on the polyurethane/poly(vinyl alcohol) (PU/PVA) blend containing silica nanoparticles. Pure (CO₂, CH₄, N₂, O₂) and mixed-gas (CO₂/N₂ and CO₂/CH₄) permeability experiments were carried out at 10 bar and 35 °C. Poly(vinyl alcohol) (PVA) with a molecular weight of 200 kDa (PVA200) was blended with polyurethane (PU) to increase the CO₂ solubility, while the addition of silica particles to the PU/PVA blend membranes augmented the CO₂ separation performance. The SEM images of the membranes showed that the miscibility of the blend improved by increasing the PVA contents. The membrane containing 10 wt % of PVA200 (PU/PVA200-10) exhibited the highest CO₂/N₂~32.6 and CO₂/CH₄~9.5 selectivities among other blend compositions, which increased to 45.1 and 15.2 by incorporating 20 wt % nano-silica particles.