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Cyclopentadienyl-ruthenium and -osmium chemistry. IV. Convenient high-yield synthesis of some cyclopentadienyl ruthenium or osmium tertiary phosphine halide complexes
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1977
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Cyclopentadienyl RutheniumInorganic ChemistryChemical EngineeringEngineeringAlkene MetathesisHigh-yield One-pot SynthesesCoordination ComplexConvenient High-yield SynthesisOrganometallic CatalysisMolecular ComplexChemistryInorganic Synthesis-Osmium ChemistryOsmium HalidesTertiary Phosphine
High-yield one-pot syntheses of RuCl(PR3)2(η-C5H5) (R = Ph or p-MeC6H4) and OsBr(PPh3)2- (η-C5H5) from ruthenium or osmium halides, the tertiary phosphine and cyclopentadiene are described.