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Layered Heterometallic Iodoplumbate Containing a Novel Pb<sub>3</sub>Cu<sub>6</sub>I<sub>16</sub> Net:  Structure and Optical Properties

73

Citations

30

References

2006

Year

Abstract

A new heterometallic iodoplumbate was synthesized solvothermally. The complex, [Co(phen)3][Pb3Cu6I16].C2H5OH, contains a novel Pb3Cu6I16 net made up of linked Pb3I11 and Cu6I11 clusters. The clusters form a BN-type layer, where the Pb3I11 and Cu6I11 clusters take the place of B and N. The layers, which are separated by [Co(phen)3]2+ cations, contain cavities in which ethanol molecules are located.

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