Publication | Closed Access
Ring‐opening of <i>N</i>‐Tosyl Aziridines with Hydroxyl Compounds Catalyzed by Acidic Ionic Liquid
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Citations
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References
2009
Year
Acidic Ionic LiquidN ‐Tosyl AziridinesEngineeringBiochemistryAbstract Ring‐openingHydroxyl Compounds CatalyzedHigh RegioselectivityNatural SciencesOrganic ChemistryChemistryHeterocycle ChemistryDeep Eutectic SolventSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract Ring‐opening of two types of N ‐tosyl aziridines with hydroxyl compounds has been studied. The aziridines could react smoothly with alcohols in the presence of functional ionic liquid [hmim]HSO 4 to afford the corresponding β ‐amino ethers in moderate to good yields with high regioselectivity. The recyclable property of [hmim]HSO 4 was demonstrated in the process.
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