A Pauson−Khand-Type Reaction between Alkynes and Olefinic Aldehydes Catalyzed by Rhodium/Cobalt Heterobimetallic Nanoparticles:  An Olefinic Aldehyde as an Olefin and CO Source

Abstract

Co/Rh (Co:Rh = 2:2) heterobimetallic nanoparticles derived from Co(2)Rh(2)(CO)(12) react with alkynes and alpha,beta-unsaturated aldehydes such as acrolein, crotonaldehyde, and cinnamic aldehyde and release products resulting from [2 + 2 + 1]cycloaddition of alkyne, carbon monoxide, and alkene. alpha,beta-Unsaturated aldehydes act as a CO and alkene source. These reactions produce 2-substituted cyclopentenones.