Publication | Closed Access
A New Transformation of Silanols. Palladium-Catalyzed Cross-Coupling with Organic Halides in the Presence of Silver(I) Oxide
167
Citations
5
References
1999
Year
Materials ScienceInorganic ChemistryChemical EngineeringCatalyst SystemEngineeringOrganic HalidesCross-coupling ReactionAlkene MetathesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisNew TransformationCoupling Products
The reactions of aryl- and alkenylsilanols with organic halides are found to proceed in a catalyst system of 5 mol % of Pd(PPh3)4 and Ag2O (1 equiv) to give the corresponding coupling products in up to 84% yield.
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