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Stereocontrolled Synthesis of Alkyl- and Aryl- α- and β-selenoglycosides.
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1992
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Corresponding Diglucopyranosyl DiselenideEngineeringNatural SciencesDiversity-oriented SynthesisOrganic ChemistryStereoselective SynthesisChemistryAlkyl HalidePharmacologyStereocontrolled SynthesisSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringComplete StereocontrolNatural Product Synthesis
Alkyl α- and β-selenoglucosides are prepared in good yield by reaction of the corresponding diglucopyranosyl diselenide with alkyl halide under reducing conditions. Complete stereocontrol is achieved in the transformation.