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Enhancement of the diastereoselectivity in the addition of trimethylsilyl cyanide to chiral aldimines by catalysis with a chiral 1,2-diamine: unexpected mechanistic results

Trimethylsilyl CyanideChemical EngineeringEnantioselective SynthesisEngineeringOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryUnexpected Mechanistic ResultsAsymmetric CatalysisChiral Aldimines