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A Facile Synthesis of 6-C-Prenylflavanones
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1997
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DerivativesClaisen RearrangementFacile SynthesisDiversity-oriented SynthesisNatural SciencesOrganic ChemistryChemistryNatural Product SynthesisCyclization ReactionDerivative (Chemistry)Synthetic ChemistryAcetophenone Derivative 6
The first total synthesis of two natural 6-C-prenylflavanones, (±)-6-C-prenyleriodoctyol (1) and 6-C-prenylnaringenin (2), using the acetophenone derivative 6 as the key intermediate is described. This new efficient synthetic approach was mainly based on Claisen rearrangement and cyclization reaction.