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Synthesis and Reactions of Thioether-Thiolate Compounds of 1,3-Dithiole-2-thione-4,5-dithiolate (dmit)
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1994
Year
Efficient MethodOrganic ChemistryUnsymmetrical Crown CompoundsVarious 1,3-Dithiole-2-thione-4-thiolate-5-thioestersChemistryHeterocycle ChemistryDerivative (Chemistry)Synthetic ChemistryEnantioselective SynthesisThioether-thiolate Compounds
An efficient method for the preparation of the unsymmetrically substituted 1,3-dithiole-2-thione-4,5-dithiolate (dmit) is reported. Its application is demonstrated by obtainment of various 1,3-dithiole-2-thione-4-thiolate-5-thioesters and ethers. Starting from these compounds an expedient route to novel unsymmetrical crown compounds and tetrathiafulvalenes is shown.