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A Rh(I)-Catalyzed Cycloisomerization Reaction Affording Cyclic Trienones
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2008
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Cross-coupling ReactionEngineeringHeterocyclicAlkene MetathesisAllene-ynones AffordsOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHeterocycle ChemistryCarbocyclization ReactionTriene-forming ProtocolBiomolecular Engineering
A Rh(I)-catalyzed carbocyclization reaction of allene-ynones affords functionalized 2-alkylidene-3-vinylcyclohexenones and 2-alkylidene-3-vinylcyclopentenones. The scope, limitations, and utility of this triene-forming protocol have been examined and the results reported within.