Publication | Closed Access
A Xanthate Transfer Radical Process for the Introduction of the Trifluoromethyl Group
69
Citations
5
References
2001
Year
EngineeringAlkene MetathesisRadical (Chemistry)Fluorous SynthesisUnactivated AlkenesOrganic ChemistryChemistryHalogenationRadical MechanismTrifluoromethyl GroupLeast Hindered TerminusBiomolecular Engineering
[reaction: see text]. S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.
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