Concepedia

A Xanthate Transfer Radical Process for the Introduction of the Trifluoromethyl Group

Frédérique Bertrand, Virginie Pévère, Béatrice Quiclet‐Sire, Samir Z. Zard

Organic Letters · 2001 · 69 citations · 5 references

DOI

Concepts

Abstract

[reaction: see text]. S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.

References

5

Trifluoromethylations and related reactions in organic chemistry

M. A. MCCLINTON, Deborah A. McClinton · Tetrahedron · 1992 · 587 citations

, , +2

The chemistry of organic fluorine compounds

Dietmar Seyferth · Journal of Organometallic Chemistry · 1977 · 256 citations

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Introduction of fluorine into organic molecules: why and how

Manfred Schlosser · Tetrahedron · 1978 · 230 citations

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Preparation of trifluoromethyl ketones and related fluorinated ketones

Jean‐Pierre Bégué, Danièle Bonnet‐Delpon · Tetrahedron · 1991 · 225 citations

, , +7

α-Fluorocarbonyl compounds and related chemistry

Shlomo Rozen, Robert Filler · Tetrahedron · 1985 · 154 citations

, , +6