Concepedia

A New Application of Dimethyl Trithiocarbonate. Methylthiothiocarbonylation of 2,4-Pentanedione and Some β-Oxoesters

Ana B. Pérez‐Oliva, Aurora Molinari, Lucas A. H. Sanchez

Synthetic Communications · 1998 · 11 citations · 9 references

Concepts

New ApplicationChemical EngineeringDerivative (Chemistry)DerivativesEngineeringDimethyl TrithiocarbonateAbstract 2,4-PentanedioneOrganic ChemistryChemistryHeterocycle ChemistrySodium AcetateChemical DerivativeSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering

Abstract

Abstract 2,4-Pentanedione, ethyl acetoacetate, benzoyl acetate and diethyl malonate 1a-d react with sodium acetate and dimethyl trithiocarbonate in dimethylformamide to afford methyl-β,β′-dicarbonyldithiocarboxylate derivatives 2a-d in moderate yield.

References

9

Preparation, metallation and alkylation of allenyl ethers

S. Hoff, L. Brandsma, J. F. Arens · Recueil des Travaux Chimiques des Pays-Bas · 1968 · 996 citations

Chemical Engineering, Engineering, Alkene Metathesis +9

Ketene Dithioacetals in Organic Synthesis: Recent Developments

Michael Kolb · Synthesis · 1990 · 182 citations

Engineering, Heterocyclic, Organic Chemistry +9

Organic Reactions of Carbon Disulfide

Masataka Yokoyama, Tsuneo Imamoto · Synthesis · 1984 · 57 citations

Chemical Transformation, Carbon Disulfide, Organic Chemistry +2

Phase-Transfer Synthesis of Symmetrical and Unsymmetrical Dialkyl Trithiocarbonates

Iacopo Degani, Rita Fochi, Antonella Gatti et al. · Synthesis · 1986 · 48 citations

Phase-transfer Synthesis, Organic Chemistry, Chemistry +3

A Facile One-Step Synthesis of Methyl β-Oxodithiocarboxylates

G. SINGH, Sudip Bhattacharjee, Hiriyakkanavar Ila et al. · Synthesis · 1982 · 39 citations

Organic Chemistry, Synthetic Chemistry, Facile One-step Synthesis +1