Reversal of enantioselectivity using tethered bisguanidine catalysts in the aza-Henry reaction

In the Golden Age of Organocatalysis

Peter I. Dalko, Lionel Moisan · Angewandte Chemie International Edition · 2004 · 2.6K citations

Natural Sciences, Chemistry, Bioorganic Chemistry +6

New Strategies for Organic Catalysis:  The First Highly Enantioselective Organocatalytic Diels−Alder Reaction

Kateri A. Ahrendt, Christopher J. Borths, David W. C. MacMillan · Journal of the American Chemical Society · 2000 · 1.7K citations

Natural Sciences, Chemistry, Biocatalysis +9

The First Direct and Enantioselective Cross-Aldol Reaction of Aldehydes

Alan B. Northrup, David W. C. MacMillan · Journal of the American Chemical Society · 2002 · 702 citations

Natural Sciences, Chemistry, Biocatalysis +12

Phase transfer catalysis

Applied Catalysis · 1990 · 698 citations

Asymmetric Catalytic Mannich Reactions Catalyzed by Urea Derivatives:  Enantioselective Synthesis of <i>β</i>-Aryl-<i>β</i>-Amino Acids

Anna G. Wenzel, Eric N. Jacobsen · Journal of the American Chemical Society · 2002 · 551 citations

Natural Sciences, Chemistry, Catalysis +10