Concepedia

1,1-Carboboration Route to Substituted Naphthalenes

René Liedtke, M. Harhausen, Roland Fröhlich, Gerald Kehr, Gerhard Erker

Organic Letters · 2012 · 45 citations · 39 references

DOI

Concepts

Abstract

1,2-Bis(alkynyl)benzene derivatives react with strongly electrophilic boranes to yield in boryl-functionalized bulky naphthalene derivatives by means of a sequence of 1,1-carboboration reactions. These substrates can be functionalized by transition metal catalyzed cross-coupling reactions.

References

39

Frustrated Lewis Pairs: Metal‐free Hydrogen Activation and More

Douglas W. Stephan, Gerhard Erker · Angewandte Chemie International Edition · 2009 · 2K citations

, , +13

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

Young Jun Park, Jung‐Woo Park, Chul‐Ho Jun · Accounts of Chemical Research · 2008 · 927 citations

, , +16

Reactive 1,4-dehydroaromatics

Robert G. Bergman · Accounts of Chemical Research · 1973 · 754 citations

, , +5

Alkylboranes in the Suzuki−Miyaura Coupling:  Stereochemical and Mechanistic Studies

Karl Matos, John A. Soderquist · The Journal of Organic Chemistry · 1998 · 350 citations

, , +9

Experimental and Computational Evidence for Gold Vinylidenes: Generation from Terminal Alkynes via a Bifurcation Pathway and Facile C–H Insertions

Long‐Wu Ye, Yanzhao Wang, Donald H. Aue et al. · Journal of the American Chemical Society · 2011 · 339 citations

, , +16