Concepedia

Rhodium-Catalyzed Reaction of Thiols with Polychloroalkanes in the Presence of Triethylamine

Ken Tanaka, Kaori Ajiki

Organic Letters · 2005 · 45 citations · 9 references

DOI

Concepts

Abstract

[reaction: see text] RhCl(PPh(3))(3) catalyzes a reaction of thiols with polychloroalkanes in the presence of triethylamine. This reaction serves as a convenient new method to produce formaldehyde dithioacetals, ethylenedithioethers, thioformates, and dithiocarbonic esters under mild conditions.

References

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