Concepedia

Synthesis of the Isolable Biradicals <sup>•</sup>(CH<sub>3</sub>B)<sub>11</sub>C−C⋮C−C(BCH<sub>3</sub>)<sub>11</sub><sup>•</sup> and <i>trans-</i><sup>•</sup>(CH<sub>3</sub>B)<sub>11</sub>C−CHCH−C(BCH<sub>3</sub>)<sub>11</sub><sup>•</sup>

Ludvig Eriksson, Kamesh Vyakaranam, Josef Michl

The Journal of Organic Chemistry · 2007 · 37 citations · 9 references

DOI

Concepts

Abstract

A synthesis of ethene and ethyne derivatives carrying the anionic -C(BCH3)11- substituent on one or both carbon atoms is described. Two-electron oxidation of the dianions yielded the stable and isolable electroneutral title biradicals.

References

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Michael L. McKee · Journal of the American Chemical Society · 1997 · 45 citations

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Voltammetry in benzene using lithium dodecamethylcarba-closo-dodecaborate, LiCB11Me12, as a supporting electrolyte: reduction of Ag+

Lubomı́r Pospı́šil, Benjamin T. King, Josef Michl · Electrochimica Acta · 1998 · 42 citations

, , +12