Concepedia

Publication | Closed Access

Generation and Carbonyl Addition of Dibromofluoromethyllithium

DOI

23

Citations

0

References

1995

Year

Manabu Kuroboshi, Nobuko Yamada, Yoko Takebe, Tamejiro Hiyama
Synlett

Abstract

When CFBr3 was treated with n-BuLi at -130 °C, thermally labile LiCFBr2 was generated which reacted smoothly with a coexisting electrophile RR’CO to give an adduct RR’C(OH)CFBr2 in good yield.