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Triethylamine‐Catalyzed Efficient Synthesis of Oxathiolanes Containing a Highly Polarized Carbon‐Carbon Double Bond from Reaction of Malononitrile, Carbon Disulfide (CS<sub>2</sub>), and Oxiranes
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Citations
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References
2011
Year
Chemical EngineeringCross-coupling ReactionEngineeringEt 3Natural SciencesDiversity-oriented SynthesisPush‐pull Cc BondCs 2Carbon DisulfideOrganic ChemistryOrganometallic CatalysisCatalysisEfficient SynthesisChemistryPharmacologySynthetic Chemistry
Abstract An efficient synthesis of functionalized 2‐(1,3‐oxathiolan‐2‐ylidene)malononitriles containing a push‐pull CC bond via a simple reaction between malononitrile, CS 2 , and oxiranes in the presence of Et 3 N is described ( Scheme 1 ).
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