Advanced Synthesis & Catalysis · 2015 · 48 citations · 76 references
Natural SciencesChemistryMedicinal ChemistryCatalysisOrganic ChemistryCatalytic MechanismsHeterocycle SynthesisOrganic SynthesisAryl Halide ActivationAryl Halide CouplingArylation ReactionsBiaryl FunctionalizationC-h ActivationMedicinal Chemistry Applications
Abstract An efficient o‐ arylation of pivalamides by aryl iodides via rhodium(III)‐catalyzed C–H activation is demonstrated for the first time. Further, the biaryl products can be converted effectively into biologically active phenanthridine and phenanthridinone derivative. magnified image
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