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Synthesis of Some New 1,4-Distyrylbenzenes Using Immobilized Palladium Nanoparticles on Silica Functionalized Morpholine as a Recyclable Catalyst
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2011
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Chemical EngineeringCatalytic ApplicationEngineeringGreen Catalyst SystemRecyclable CatalystGreen ChemistrySustainable SynthesisCatalyst RecyclingOrganic ChemistryRecycled CatalystCatalysisChemistryNew 1,4-Distyrylbenzene DerivativesSynthesis MethodCatalyst PreparationCatalytic SynthesisSilica Functionalized Morpholine
Some new 1,4-distyrylbenzene derivatives were synthesized by using immobilized palladium nanoparticles on silica-bonded N-propyl morpholine (PNP-SBNPM) as a heterogeneous catalyst. These one-pot reactions afforded a range of stereoselective, symmetrical (E)-1,4-distyrylbenzene derivatives with high yields (78-90%). The green catalyst system is recyclable and allows facile product isolation. The recycled catalyst could be reused six times without appreciable loss of catalytic activity.