Concepedia

Palladium-Catalyzed Synthesis of Arylamines from Diphenyliodonium Tetrafluoroborate and Secondary Amine

Suk‐Ku Kang, Hong-Woo Lee, Wonkyu Choi, Ryung-Kee Hong, Jae-Sun Kim

Synthetic Communications · 1996 · 20 citations · 14 references

DOI

Concepts

Abstract

Abstract The hetero-cross coupling reaction of diphenyliodonium tetrafluoro-borate with secondary amine in the presence of LiNTMS2 or NaOtBu as base, Pd2(dba)3°CHCl3 as catalyst, and tri-o-tolylphosphine as ligand afforded arylamines at room temperature under mild conditions.

References

14

Tetrahedron report number 163

James T. Lindley · Tetrahedron · 1984 · 2.2K citations

, , +1

A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines

Anil S. Guram, Roger A. Rennels, Stephen L. Buchwald · Angewandte Chemie International Edition in English · 1995 · 1K citations

, , +7

Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents

Janis Louie, John F. Hartwig · Tetrahedron Letters · 1995 · 887 citations · Full text

, , +10

Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides

Frédéric Paul, Joe Patt, John F. Hartwig · Journal of the American Chemical Society · 1994 · 835 citations

, , +14

Palladium-Catalyzed Aromatic Aminations with in situ Generated Aminostannanes

Anil S. Guram, Stephen L. Buchwald · Journal of the American Chemical Society · 1994 · 760 citations

, , +6