Publication | Closed Access
Ambient electrohydrogenation of N<sub>2</sub> for NH<sub>3</sub> synthesis on non-metal boron phosphide nanoparticles: the critical role of P in boosting the catalytic activity
112
Citations
45
References
2019
Year
Materials ScienceAmbient ElectrohydrogenationChemical EngineeringOxygen Reduction ReactionBoron Phosphide NanoparticlesEngineeringCritical RoleReversible Hydrogen ElectrodeNanoheterogeneous CatalysisCatalysisCatalytic ActivityChemistryHydrogenWater ElectrolysisElectrode Reaction MechanismHigh Faradaic EfficiencyElectrochemistry
As a non-metal electrocatalyst for the N<sub>2</sub> reduction reaction, boron phosphide nanoparticles offer a high NH<sub>3</sub> yield of 26.42 μg h<sup>−1</sup> mg<sub>cat.</sub><sup>−1</sup> and a high faradaic efficiency of 12.7% at –0.60 V <italic>vs.</italic> the reversible hydrogen electrode in 0.1 M HCl.
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