N-Heterocyclic Carbene Catalyzed Reaction of Enals and Diaryl-1,2 diones via Homoenolate: Synthesis of 4,5,5-Trisubstituted<b> γ</b>-Butyrolactones - Concepedia

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N-Heterocyclic Carbene Catalyzed Reaction of Enals and Diaryl-1,2 diones via Homoenolate: Synthesis of 4,5,5-Trisubstituted<b> γ</b>-Butyrolactones

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References

2007

Year

Vijay Nair, Sreekumar Vellalath, Manojkumar Poonoth, Eringathodi Suresh, S. Viji

EngineeringHeterocyclicDiaryl-1,2 DionesOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHeterocycle Chemistry4,4,5-Trisubstituted γ-ButyrolactonesBiomolecular EngineeringNucleophilic Heterocyclic CarbeneEnals Proceeds

Abstract

Nucleophilic heterocyclic carbene (NHC)-catalyzed annulation of enals proceeds with variety of 1,2-dicarbonyl compounds, leading to the formation of 4,4,5-trisubstituted γ-butyrolactones.