A General Synthesis of Amines and Hydrazines by Oxidation of Amidocuprates and Zinc-Amidocuprates

Abstract

All articles of this category A wide range of amines and hydrazines were synthesized according to an electrophilic amination protocol by oxidative decomposition of readily generated lithium- and zinc-amidocyanocuprates. Optimization of the yields was achieved by the appropriate combination of the organometallic cluster and the nature of the oxidizing agent. electrophilic amination - amines - hydrazines - amidocuprates - zinc-amidocuprates oxidates