Chemistry Letters · 1990 · 66 citations · 1 references
Inorganic ChemistrySilyl AcetalsEngineeringCatalytic AmountConvenient MethodEffective CatalystOrganic ChemistryOrganometallic CatalysisCatalysisKetene Silyl AcetalsChemistryHalogenationAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringGood Yields
Abstract In the presence of a catalytic amount of iron(II) iodide or trityl hexachloroantimonate, ketene silyl acetals smoothly react with imines to afford the corresponding β-aminoesters in good yields with anti-selectivities.
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