Synlett · 2001 · 99 citations · 0 references
Inorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisHighly EfficientOrganic ChemistryOrganometallic CatalysisCatalysisRuthenium AlkylideneChemistryMetathesis ReactionsCatalyst PreparationHomogeneous CatalysisElectron Deficient AlkenesPolymer ChemistryCatalytic Synthesis
Polymer supported ruthenium alkylidene catalysts 6 and 8 have been prepared and for the first time applied to cross metathesis reactions with electron deficient alkenes. These robust complexes are re-usable, highly active and tolerate a wide variety of functional groups.