Concepedia

Barbier-type Carbonyl-allylation with Allyl Compounds and SnCl2 in the Presence of PdCl2[PPh2(m-C6H4SO3Na)]2 under Two-phase Conditions

Tamon Okano, Jitsuo Kiji, T. DOI

Chemistry Letters · 1998 · 25 citations · 7 references

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Abstract

Abstract The hydrophilic palladium complex efficiently catalyzes the allylation of carbonyl compounds with allyl chlorides or allyl alcohols and SnCl2 under aqueous-organic biphase conditions, which allow us easily to separate the product and to recover the organic solvent from the reaction mixture.

References

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