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Diels-Alder Reaction of Methoxythiophenes: A New One-Pot Synthesis of Dimethyl Phthalates
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1997
Year
Chemical EngineeringDerivative (Chemistry)EngineeringAlkene MetathesisDimethyl PhthalatesNew One-pot SynthesisChemical DerivativeDimethyl AcetylenedicarbocylateOrganic ChemistryCatalysisChemistryAcetic AcidSynthetic ChemistryPolymer ChemistryBiomolecular EngineeringDiels-alder Reaction
A series of dimethyl phthalates have been prepared from methoxythiophenes and dimethyl acetylenedicarbocylate (DMAD) in xylene. When the reaction is carried out in acetic acid, thienylfumarates are obtained.