Concepedia

Radical β-elimination of vicinal phenylselenide and xanthate azides in sugar derivatives

Francisco Santoyo‐González, Francisco G. Calvo‐Flores, Fernando Hernández-Matéo, P. GARCIA‐MENDOZA, Joaquín lsac-García, Ma Dolores Pérez-Alvarez

Synlett · 1994 · 13 citations · 0 references

Concepts

Derivative (Chemistry)Natural Product SynthesisDerivativesEngineeringVicinal PhenylselenideAlkene MetathesisPharmaceutical ChemistryChemical DerivativeSugar DerivativesOrganic ChemistryXantathe AzidesPharmacologyRadical β-EliminationSynthetic ChemistryBiomolecular EngineeringRadical ß-Elimination

Abstract

Vicinal phenylselenide and xantathe azides undergo a radical ß-elimination by treatment with Bu3SnH yielding olefins.