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Copper-Assisted Arylation of 1-Thiosugars: Efficient Route to Triazene Substituted Arylthioglycosides
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2003
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Copper-assisted ArylationO-haloaryl TriazenesEngineeringSugar ThiolsOrganic ChemistryOrganometallic CatalysisCatalysisClick ChemistryChemistryAsymmetric CatalysisEfficient CopperSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Efficient copper mediated arylation of sugar thiols by o-haloaryl triazenes under mild conditions is described. The developed method allows the preparation of symmetrical and unsymmetrical 1,3-bis(glycopyranosylthio)benzene derivatives.