Asymmetric construction of chiral C–N axes through rhodium-catalyzed 1,4-addition

Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones

Yoshiaki Takaya, Masamichi Ogasawara, Tamio Hayashi et al. · Journal of the American Chemical Society · 1998 · 684 citations

Natural Sciences, Chemistry, Catalysis +9

Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-π-allylrhodium, and Hydroxorhodium Intermediates

Tamio Hayashi, Makoto Takahashi, Yoshiaki Takaya et al. · Journal of the American Chemical Society · 2002 · 585 citations

Natural Sciences, Chemistry, Catalysis +15

A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts:  Its Preparation and Use for the Rhodium-Catalyzed Asymmetric 1,4-Addition

Tamio Hayashi, Kazuhito Ueyama, Norihito Tokunaga et al. · Journal of the American Chemical Society · 2003 · 464 citations

Natural Sciences, Chemistry, Catalysis +16

Readily Available [2.2.2]-Bicyclooctadienes as New Chiral Ligands for Ir(I):  Catalytic, Kinetic Resolution of Allyl Carbonates

Christian Fischer, Christian Defieber, Takeyuki Suzuki et al. · Journal of the American Chemical Society · 2004 · 438 citations

Natural Sciences, Chemistry, Catalysis +10

<i>C</i>₂-Symmetric Bicyclo[2.2.2]octadienes as Chiral Ligands:  Their High Performance in Rhodium-Catalyzed Asymmetric Arylation of <i>N</i>-Tosylarylimines

Norihito Tokunaga, Yusuke Otomaru, Kazuhiro Okamoto et al. · Journal of the American Chemical Society · 2004 · 426 citations

Natural Sciences, Chemistry, Catalysis +13