Publication | Closed Access
Influencing the Size of Giant Rings by Manipulating Their Curvatures: Na<sub>6</sub>[Mo<sub>120</sub>O<sub>366</sub>(H<sub>2</sub>O)<sub>48</sub>H<sub>12</sub>{Pr(H<sub>2</sub>O)<sub>5</sub>}<sub>6</sub>]·(∼200H<sub>2</sub>O) with Open Shell Metal Centers at the Cluster Surface
81
Citations
7
References
2000
Year
EngineeringTheoretical Inorganic ChemistryNew TypePr3+ CationsChemistryInorganic MaterialInorganic CompoundCluster SurfaceGiant RingsMaterials ScienceInorganic ChemistryCluster SciencePhysicsTetradecameric Molybdenum-blue-type SpeciesCrystallographyCrystal Structure DesignNatural SciencesSurface ScienceCluster ChemistryMain Group Chemistry
A new type of giant-wheel-shaped anion (see title) is obtained during the formation of the "classical" tetradecameric molybdenum-blue-type species [{Mo2}{Mo8}{Mo1}]14 in the presence of Pr3+. The Pr3+ cations substitute {Mo2} units and thereby increase the curvature of each ring, which leads to destruction and smaller ring sizes.
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